The proton-proton chain is the dominant hydrogen-fusion pathway in the Sun and other relatively low-mass main-sequence stars.
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Positive nuclei repel electrically, so fusion requires high temperatures and quantum tunneling to reach nuclear interaction distances.
supportedSolar luminosity matches the energy expected from hydrogen fusion, solar neutrinos are detected with energies characteristic of proton-proton-chain reactions, and helioseismology confirms interior conditions required by solar models.